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Selective bromochlorination of a homoallylic alcohol for the total synthesis of (−)-anverene

The scope of a recently reported method for the catalytic enantioselective bromochlorination of allylic alcohols is expanded to include a specific homoallylic alcohol. Critical factors for optimization of this reaction are highlighted. The utility of the product bromochloride is demonstrated by the...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Seidl, Frederick J, Burns, Noah Z
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4979643/
https://ncbi.nlm.nih.gov/pubmed/27559385
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.129
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