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11-Step Total Synthesis of (−)-Maoecrystal V

[Image: see text] An expedient, practical, and enantioselective route to the highly congested ent-kaurane diterpene maoecrystal V is presented. This route, which has been several years in the making, is loosely modeled after a key pinacol shift in the proposed biosynthesis. Only 11 steps, many of wh...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Cernijenko, Artiom, Risgaard, Rune, Baran, Phil S.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2016
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4974602/
https://ncbi.nlm.nih.gov/pubmed/27457680
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b06623
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