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A Synthesis of the Carbon Skeleton of Maoecrystal V

[Image: see text] An enantioselective synthesis of the maoecrystal V (1) carbon skeleton is described. The key transformations include arylation of a 1,3-dicarbonyl compound with a triarylbismuth(V)dichloride species, oxidative dearomatization of a phenol, and a subsequent intramolecular Diels-Alder...

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Bibliographic Details
Main Authors: Krawczuk, Paul J., Schöne, Niklas, Baran, Phil S.
Format: Artigo
Language:Inglês
Published: 2009
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2783297/
https://ncbi.nlm.nih.gov/pubmed/19795876
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol901963v
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