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X-Ray Crystallographic, Multifrequency EPR, and DFT Characterization of the Ni(P(Cy)(2)N(t)(Bu)(2))(2)(n)(+) Hydrogen Oxidation Catalyst in the Ni(I) Oxidation State
The Ni(I) hydrogen oxidation catalyst [Ni(P(Cy)(2)N(t)(Bu)(2))(2)](+) (1(+); P(Cy)(2)N(tBu)(2)= 1,5bis(tert-butyl)-3,7-dicyclo-hexyl-1,5-diaza-3,7-diphosphacychlooctane) has been studied using a combination of EPR techniques (X-, Q-, and D-band; electron-nuclear double resonance, hyperfine sublevel...
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| 出版年: | Inorg Chem |
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| 主要な著者: | , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2015
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4972093/ https://ncbi.nlm.nih.gov/pubmed/26098955 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b00445 |
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