X-Ray Crystallographic, Multifrequency EPR, and DFT Characterization of the Ni(P(Cy)(2)N(t)(Bu)(2))(2)(n)(+) Hydrogen Oxidation Catalyst in the Ni(I) Oxidation State

The Ni(I) hydrogen oxidation catalyst [Ni(P(Cy)(2)N(t)(Bu)(2))(2)](+) (1(+); P(Cy)(2)N(tBu)(2)= 1,5bis(tert-butyl)-3,7-dicyclo-hexyl-1,5-diaza-3,7-diphosphacychlooctane) has been studied using a combination of EPR techniques (X-, Q-, and D-band; electron-nuclear double resonance, hyperfine sublevel...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Niklas, Jens, Westwood, Mark, Mardis, Kristy L., Brown, Tiara L., Pitts-McCoy, Anthony M., Hopkins, Michael D., Poluektov, Oleg G.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4972093/
https://ncbi.nlm.nih.gov/pubmed/26098955
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b00445
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