Loading...
Stereoselective Synthesis of Trisubstituted Vinyl Bromides by Addition of Alkynes to Oxocarbenium Ions
We have developed an efficient method for the synthesis of (E)-trisubstituted vinyl bromides via a Friedel–Crafts-type addition of alkynes to oxocarbenium ions formed in situ from acetals. The success of this reaction relies on identification of MgBr(2)·OEt(2) as both a Lewis acid promoter and bromi...
Na minha lista:
| Udgivet i: | Synlett |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
|
| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4961304/ https://ncbi.nlm.nih.gov/pubmed/27482143 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0035-1560265 |
| Tags: |
Tilføj Tag
Ingen Tags, Vær først til at tagge denne postø!
|