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Synthesis of Aryldifluoroamides by Copper-Catalyzed Cross-Coupling()

A copper-catalyzed coupling of aryl, heteroaryl, and vinyl iodides with α-silyldifluoroamides is reported. The reaction forms α,α-difluoro-α-aryl amides from electron-rich, electron-poor, and sterically hindered aryl iodides in high yield and tolerates a variety of functional groups. The aryldifluor...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Arlow, Sophie I., Hartwig, John F.
Formato: Artigo
Idioma:Inglês
Publicado: 2016
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4956475/
https://ncbi.nlm.nih.gov/pubmed/26929068
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201600105
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