Spectroscopic and Crystal Field Consequences of Fluoride Binding by [Yb⋅DTMA](3+) in Aqueous Solution

Yb⋅DTMA forms a ternary complex with fluoride in aqueous solution by displacement of a bound solvent molecule from the lanthanide ion. [Yb⋅DTMA⋅F](2+) and [Yb⋅DTMA⋅OH(2)](3+) are in slow exchange on the relevant NMR timescale (<2000 s(−1)), and profound differences are observed in their respectiv...

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Publicado no:Angew Chem Weinheim Bergstr Ger
Main Authors: Blackburn, Octavia A., Chilton, Nicholas F., Keller, Katharina, Tait, Claudia E., Myers, William K., McInnes, Eric J. L., Kenwright, Alan M., Beer, Paul D., Timmel, Christiane R., Faulkner, Stephen
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY‐VCH Verlag 2015
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4955232/
https://ncbi.nlm.nih.gov/pubmed/27478267
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ange.201503421
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