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Catalytic Enantioselective Dihalogenation and the Selective Synthesis of (–)-Deschloromytilipin A and (–)-Danicalipin A

A titanium-based catalytic enantioselective dichlorination of simple allylic alcohols is described. This dichlorination reaction provides stereoselective access to all common dichloroalcohol building blocks used in syntheses of chlorosulfolipid natural products. An enantioselective synthesis of ent-...

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Pubblicato in:J Am Chem Soc
Autori principali: Landry, Matthew L., Hu, Dennis X., McKenna, Grace M., Burns, Noah Z.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2016
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4922634/
https://ncbi.nlm.nih.gov/pubmed/27018981
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b01643
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