A Model for Active-site Formation Process in DMSO Reductase Family Molybdenum Enzymes Involving Oxido-alcoholato- and Oxido-thiolato-molybdenum(VI) Core Structures

New bis(ene-1,2-dithiolato)-oxido-alcoholato-molybdenum(VI) and -oxido-thiolato-molybdenum(VI) anionic complexes, denoted as [Mo(VI)O(ER)L(2)](−) (E = O, S; L = dimethoxycarboxylate-1,2-ethylenedithiolate), have been obtained from the reaction of the corresponding dioxido-moybdenum(VI) precursor com...

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Publicado en:Inorg Chem
Main Authors: Sugimoto, Hideki, Sato, Masanori, Asano, Kaori, Suzuki, Takeyuki, Mieda, Kaoru, Ogura, Takashi, Matsumoto, Takashi, Giles, Logan J., Pokhrel, Amrit, Kirk, Martin L., Itoh, Shinobu
Formato: Artigo
Idioma:Inglês
Publicado: 2016
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4912129/
https://ncbi.nlm.nih.gov/pubmed/26816115
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b02395
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