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(19)F NMR-, ESR-, and vis-NIR-spectroelectrochemical study of the unconventional reduction behaviour of a perfluoroalkylated fullerene: dimerization of the C(70)(CF(3))(10) (–) radical anion
The most abundant isomer of C(70)(CF(3))(10) (70-10-1) is a rare example of a perfluoroalkylated fullerene exhibiting electrochemically irreversible reduction. We show that electrochemical reversibility at the first reduction step is achieved at scan rates higher than 500 V s(–1). Applying ESR-, vis...
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| Foilsithe in: | Analyst |
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| Main Authors: | , , , , , , |
| Formáid: | Artigo |
| Teanga: | Inglês |
| Foilsithe: |
Royal Society of Chemistry
2015
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| Ábhair: | |
| Rochtain Ar Líne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4910863/ https://ncbi.nlm.nih.gov/pubmed/26359514 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5an01129a |
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