(19)F NMR-, ESR-, and vis-NIR-spectroelectrochemical study of the unconventional reduction behaviour of a perfluoroalkylated fullerene: dimerization of the C(70)(CF(3))(10) (–) radical anion

The most abundant isomer of C(70)(CF(3))(10) (70-10-1) is a rare example of a perfluoroalkylated fullerene exhibiting electrochemically irreversible reduction. We show that electrochemical reversibility at the first reduction step is achieved at scan rates higher than 500 V s(–1). Applying ESR-, vis...

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Bibliographic Details
Published in:Analyst
Main Authors: Zalibera, Michal, Machata, Peter, Clikeman, Tyler T., Rosenkranz, Marco, Strauss, Steven H., Boltalina, Olga V., Popov, Alexey A.
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2015
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4910863/
https://ncbi.nlm.nih.gov/pubmed/26359514
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5an01129a
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