Synthetic Studies on Tricyclic Diterpenoids: Direct Allylic Amination Reaction of Isopimaric Acid Derivatives

A selective synthesis of 7‐ or 14‐nitrogen containing tricyclic diterpenoids was completed according to a strategy in which the key step was the catalyzed direct allylic amination of methyl 14α‐hydroxy‐15,16‐dihydroisopimarate with a wide variety of nitrogenated nucleophiles. It was revealed that th...

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Publicat a:ChemistryOpen
Autors principals: Timoshenko, Mariya A., Kharitonov, Yurii V., Shakirov, Makhmut M., Bagryanskaya, Irina Yu., Shults, Elvira E.
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2015
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Full Papers
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4906488/
https://ncbi.nlm.nih.gov/pubmed/27308214
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201500187
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