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Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism

The palladium-catalysed allylic substitution reaction is one of the most important reactions in transition-metal catalysis and has been well-studied in the past decades. Most of the reactions proceed through an outer-sphere mechanism, affording linear products when monosubstituted allyl reagents are...

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Vydáno v:Nat Commun
Hlavní autoři: Bai, Da-Chang, Yu, Fei-Le, Wang, Wan-Ying, Chen, Di, Li, Hao, Liu, Qing-Rong, Ding, Chang-Hua, Chen, Bo, Hou, Xue-Long
Médium: Artigo
Jazyk:Inglês
Vydáno: Nature Publishing Group 2016
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4906412/
https://ncbi.nlm.nih.gov/pubmed/27283477
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms11806
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