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Regiodefined synthesis of brominated hydroxyanthraquinones related to proisocrinins

Dibromobenzoisofuranone 12, synthesized in six steps, was regiospecifically annulated with 5-substituted cyclohexenones 13/36 in the presence of LiOt-Bu to give brominated anthraquinones 14/38 in good yields. Darzens condensation of 30 was shown to give chain-elongated anthraquinone 32. Alkaline hyd...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Roy, Joyeeta, Mal, Tanushree, Jana, Supriti, Mal, Dipakranjan
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4901998/
https://ncbi.nlm.nih.gov/pubmed/27340445
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.52
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