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Diradical reaction mechanisms in [3 + 2]-cycloadditions of hetaryl thioketones with alkyl- or trimethylsilyl-substituted diazomethanes

Reactions of dihetaryl and aryl/hetaryl thioketones with 2-diazopropane, diazoethane, and (trimethylsilyl)diazomethane were studied at variable temperature. The experiments showed that reactions with 2-diazopropane carried out at –75 °C occur mainly via the initially formed, relatively stable 1,3,4-...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Mlostoń, Grzegorz, Pipiak, Paulina, Heimgartner, Heinz
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4901872/
https://ncbi.nlm.nih.gov/pubmed/27340463
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.71
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