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Investigation of the Mechanism of Electron Capture and Electron Transfer Dissociation of Peptides with a Covalently Attached Free Radical Hydrogen Atom Scavenger

The mechanisms of electron capture and electron transfer dissociation (ECD and ETD) are investigated by covalently attaching a free-radical hydrogen atom scavenger to a peptide. The 2,2,6,6-tetramethylpiperidin-l-oxyl (TEMPO) radical was chosen as the scavenger due to its high hydrogen atom affinity...

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Publicat a:Int J Mass Spectrom
Autors principals: Sohn, Chang Ho, Yin, Sheng, Peng, Ivory, Loo, Joseph A., Beauchamp, J. L.
Format: Artigo
Idioma:Inglês
Publicat: 2015
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4892187/
https://ncbi.nlm.nih.gov/pubmed/27275130
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ijms.2015.07.007
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