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Late-Stage Diversification of Biologically Active Molecules via Chemoenzymatic C-H Functionalization

Engineered variants of rebeccamycin halogenase were used to selectively halogenate a number of biologically active aromatic compounds. Subsequent Pd-catalyzed cross-coupling reactions on the crude extracts of these reactions were used to install aryl, amine, and ether substituents at the halogenatio...

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Publicat a:ACS Catal
Autors principals: Durak, Landon J., Payne, James T., Lewis, Jared C.
Format: Artigo
Idioma:Inglês
Publicat: 2016
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4890977/
https://ncbi.nlm.nih.gov/pubmed/27274902
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.5b02558
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