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Controlled Rh-Catalyzed Mono and Double Decarbonylation of Alkynyl α-Diones to Form Conjugated Ynones and Disubstituted Alkynes
A Rh-catalyzed controlled decarbonylation of alkynyl α-diones is described. By using different ligand and solvent combinations, mono and double decarbonylation can be selectively achieved to give conjugated ynones and disubstituted alkynes, respectively. A fundamental study on catalytic activation o...
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| Publicado en: | Org Lett |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2015
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4877303/ https://ncbi.nlm.nih.gov/pubmed/26503477 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b02911 |
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