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Ruthenium-Catalyzed Multicomponent Reaction: Access to α-Silyl-β-Hydroxy Vinylsilanes, Stereodefined 1,3-Dienes and Cyclohexenes

The synthesis of α-silyl-β-hydroxyl vinylsilanes was achieved in a ruthenium-catalyzed multicomponent reaction (MCR). The utility of these substrates was explored in further synthetic manipulations giving rise to stereodefined olefins and cyclohexene derivatives in one-pot. A MCR with four component...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Trost, Barry M., Koester, Dennis C., Sharif, Ehesan U.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4866645/
https://ncbi.nlm.nih.gov/pubmed/26669265
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201504981
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