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Structurally Diverse Diazafluorene-Ligated Palladium(II) Complexes and their Implications for Aerobic Oxidation Reactions

4,5-Diazafluoren-9-one (DAF) has been identified as a highly effective ligand in a number of Pd-catalyzed oxidation reactions, but the mechanistic basis for its utility has not been elucidated. Here, we present the complex coordination chemistry of DAF and palladium(II) carboxylate salts. Multiple c...

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Vydáno v:J Am Chem Soc
Hlavní autoři: White, Paul B., Jaworski, Jonathan N., Fry, Charles G., Dolinar, Brian S., Guzei, Ilia A., Stahl, Shannon S.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2016
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4863657/
https://ncbi.nlm.nih.gov/pubmed/26967703
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b01188
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