Optimized Synthesis of a Pentafluoro-gem-diol and Conversion to a CF(2)Br-Glucopyranose through Trifluoroacetate-Release and Halogenation

Pentafluoro-gem-diols are substrates that enable the synthesis of valuable difluoromethylene-containing organic molecules through the release of trifluoroacetate. Currently, only one synthetic strategy is available to assemble these important precursors. Herein, two new synthetic strategies to a com...

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Publicado en:Tetrahedron Lett
Main Authors: Hazlitt, Robert A., John, Jinu P., Tran, Que-Lynn, Colby, David A.
Formato: Artigo
Idioma:Inglês
Publicado: 2016
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4863236/
https://ncbi.nlm.nih.gov/pubmed/27182091
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2016.03.064
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