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Unusual hydroxyl effect on fulvene endoperoxide decompositions
The thermal decomposition of fulvene endoperoxides ordinarily proceeds via an allene oxide intermediate affording oxepin-2(3H)-one derivatives. We have now uncovered new, unusual pathways in these decompositions where the presence of a hydroxyl group on the alkyl or aryl attached to the fulvene exoc...
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| Publicado no: | Tetrahedron Lett |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4860729/ https://ncbi.nlm.nih.gov/pubmed/27175039 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2016.04.024 |
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