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An alternative synthesis and x-ray crystallographic confirmation of (−)-stepholidine

A formal enantioselective synthesis of (−)-stepholidine that provides an alternative preparation of key lactone intermediate 2 is described. The stereostructure of (−)-stepholidine prepared via this method was confirmed by x-ray diffraction.

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Detalhes bibliográficos
Publicado no:Tetrahedron Lett
Main Authors: Gadhiya, Satishkumar V, Hu, Chunhua, Harding, Wayne W
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4852479/
https://ncbi.nlm.nih.gov/pubmed/27152055
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2016.03.108
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