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Convenient synthesis of phosphonohydrazines from arylamines

Phosphonohydrazines were prepared in good yield from corresponding arylamines by a one-pot reaction through diazotization with an organic nitrite and treatment with a trialkyl phosphite. The trialkyl phosphite is postulated to function as a nucleophile as well as a reducing agent.

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Detalhes bibliográficos
Publicado no:Tetrahedron Lett
Main Authors: Kent, Greggory T., Blackburn, Daniel J., Gonzalez, Joseph R., Mayer, Megan L., Wu, Weiming
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4838999/
https://ncbi.nlm.nih.gov/pubmed/27110042
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2016.03.111
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