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A mononuclear nonheme iron(III)-superoxo complex: Crystallographic and spectroscopic characterization and reactivities
Mononuclear nonheme iron(III)-superoxo species (Fe(III)-O(2)(−•)) have been implicated as key intermediates in the catalytic cycles of dioxygen activation by nonheme iron enzymes. Although nonheme iron(III)-superoxo species have been trapped and characterized spectroscopically in enzymatic and biomi...
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| Publicat a: | Nat Commun |
|---|---|
| Autors principals: | , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2014
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4838200/ https://ncbi.nlm.nih.gov/pubmed/25510711 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms6440 |
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