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A Manganese Catalyst for Highly Reactive Yet Chemoselective Intramolecular C(sp(3))—H Amination
C—H bond oxidation reactions underscore the existing paradigm wherein high reactivity and high selectivity are inversely correlated. The development of catalysts capable of oxidizing strong aliphatic C(sp(3))—H bonds while displaying chemoselectivity (i.e. tolerance of more oxidizable functionality)...
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| Publicado no: | Nat Chem |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4836951/ https://ncbi.nlm.nih.gov/pubmed/26587714 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.2366 |
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