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A Manganese Catalyst for Highly Reactive Yet Chemoselective Intramolecular C(sp(3))—H Amination

C—H bond oxidation reactions underscore the existing paradigm wherein high reactivity and high selectivity are inversely correlated. The development of catalysts capable of oxidizing strong aliphatic C(sp(3))—H bonds while displaying chemoselectivity (i.e. tolerance of more oxidizable functionality)...

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Publicado en:Nat Chem
Autores principales: Paradine, Shauna M., Griffin, Jennifer R., Zhao, Jinpeng, Petronico, Aaron L., Miller, Shannon M., White, M. Christina
Formato: Artigo
Lenguaje:Inglês
Publicado: 2015
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4836951/
https://ncbi.nlm.nih.gov/pubmed/26587714
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.2366
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