A Manganese Catalyst for Highly Reactive Yet Chemoselective Intramolecular C(sp(3))—H Amination

C—H bond oxidation reactions underscore the existing paradigm wherein high reactivity and high selectivity are inversely correlated. The development of catalysts capable of oxidizing strong aliphatic C(sp(3))—H bonds while displaying chemoselectivity (i.e. tolerance of more oxidizable functionality)...

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Bibliographic Details
Published in:Nat Chem
Main Authors: Paradine, Shauna M., Griffin, Jennifer R., Zhao, Jinpeng, Petronico, Aaron L., Miller, Shannon M., White, M. Christina
Format: Artigo
Language:Inglês
Published: 2015
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4836951/
https://ncbi.nlm.nih.gov/pubmed/26587714
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.2366
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