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The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium‐to‐Gold Transmetalation

The dirhodium carbene derived from bis(4‐methoxyphenyl)diazomethane and [Rh(tpa)(4)]⋅CH(2)Cl(2) (tpa=triphenylacetate) was characterized by UV, IR, and NMR spectroscopy, HRMS, as well as by X‐ray diffraction. The isolated complex exhibits prototypical rhodium carbene reactivity in that it cyclopropa...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Werlé, Christophe, Goddard, Richard, Fürstner, Alois
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY‐VCH Verlag 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4832834/
https://ncbi.nlm.nih.gov/pubmed/26534892
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201506902
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