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Nickel-Catalyzed Activation of Acyl C–O Bonds of Methyl Esters
We report the first catalytic method for activating the acyl C–O bonds of methyl esters through an oxidative addition process. The oxidative addition adducts, formed using nickel catalysis, undergo in situ trapping to provide anilide products. DFT calculations are used to support the proposed reacti...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4821830/ https://ncbi.nlm.nih.gov/pubmed/26804615 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201511486 |
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