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Nickel-Catalyzed Activation of Acyl C–O Bonds of Methyl Esters

We report the first catalytic method for activating the acyl C–O bonds of methyl esters through an oxidative addition process. The oxidative addition adducts, formed using nickel catalysis, undergo in situ trapping to provide anilide products. DFT calculations are used to support the proposed reacti...

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Dades bibliogràfiques
Publicat a:Angew Chem Int Ed Engl
Autors principals: Hie, Liana, Fine Nathel, Noah F., Hong, Xin, Yang, Yun-Fang, Houk, K. N., Garg, Neil K.
Format: Artigo
Idioma:Inglês
Publicat: 2016
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4821830/
https://ncbi.nlm.nih.gov/pubmed/26804615
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201511486
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