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Development of an Intermittent-Flow Enantioselective Aza-Henry Reaction Using an Arylnitromethane and Homogeneous Brønsted Acid–Base Catalyst with Recycle

A stereoselective aza-Henry reaction between an arylnitromethane and Boc-protected aryl aldimine using a homogeneous Brønsted acid–base catalyst was translated from batch format to an automated intermittent-flow process. This work demonstrates the advantages of a novel intermittent-flow setup with p...

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Detalhes bibliográficos
Publicado no:Org Process Res Dev
Main Authors: Tsukanov, Sergey V., Johnson, Martin D., May, Scott A., Rosemeyer, Morgan, Watkins, Michael A., Kolis, Stanley P., Yates, Matthew H., Johnston, Jeffrey N.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4821467/
https://ncbi.nlm.nih.gov/pubmed/27065720
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.oprd.5b00245
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