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Ligand-Enabled Arylation of γ-C–H Bonds
Pd(II)-catalyzed arylation of γ-C(sp(3))–H bond of aliphatic acid-derived amides is developed by using quinoline-based ligands. Various γ-aryl-α-amino acids are prepared from natural amino acids using this method. The influence of ligand structure on reactivity is also systematically investigated....
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4821162/ https://ncbi.nlm.nih.gov/pubmed/26919066 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201512020 |
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