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Synthesis of Rumphellaone A and Hushinone by a Gold-Catalyzed [2 + 2] Cycloaddition
[Image: see text] The enantioselective total synthesis of rumphellaone A has been accomplished in 12 steps via a diastereoselective gold(I)-catalyzed [2 + 2] macrocyclization of a 1,10-enyne as the key step to build the cyclobutene moiety. This concise approach has also led to the total synthesis of...
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| Published in: | Org Lett |
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| Main Authors: | , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
American
Chemical Society
2016
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| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4820790/ https://ncbi.nlm.nih.gov/pubmed/26974011 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b00473 |
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