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Spin-Selective Generation of Triplet Nitrenes: Olefin Aziridination via Visible Light Photosensitization of Azidoformates
Azidoformates are interesting potential nitrene precursors, but their direct photochemical activation can result in competitive formation of aziridination and allylic amination products. Here, we show that visible light activated transition metal complexes can be triplet sensitizers that selectively...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4811335/ https://ncbi.nlm.nih.gov/pubmed/26732649 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201510868 |
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