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Direct Acylation of C(sp(3))–H Bonds Enabled by Nickel and Photoredox Catalysis

Using nickel and photoredox catalysis, the direct functionalization of C(sp(3))–H bonds of N-aryl amines by acyl electrophiles is described. The method affords a diverse range of α-amino ketones at room temperature and is amenable to late-stage coupling of complex and biologically relevant groups. C...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Joe, Candice L., Doyle, Abigail G.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2016
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC4807873/
https://ncbi.nlm.nih.gov/pubmed/26890705
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201511438
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