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Application of a high-throughput enantiomeric excess optical assay involving a dynamic covalent assembly: parallel asymmetric allylation and ee sensing of homoallylic alcohols

Asymmetric Ir-catalyzed C–C coupling of primary alcohols with allyl-acetates, as described by Krische, to form chiral secondary homo-allylic alcohols were performed in parallel as a means to optimize the ee values thereof. Specifically, approximately 400 examples of this reaction were performed by v...

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Publicat a:Chem Sci
Autors principals: Jo, H. H., Gao, X., You, L., Anslyn, E. V., Krische, M. J.
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2015
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4800411/
https://ncbi.nlm.nih.gov/pubmed/27014433
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02416a
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