One‐Electron Oxidation of [M(P(t)Bu(3))(2)] (M=Pd, Pt): Isolation of Monomeric [Pd(P(t)Bu(3))(2)](+) and Redox‐Promoted C−H Bond Cyclometalation

Oxidation of zero‐valent phosphine complexes [M(P(t)Bu(3))(2)] (M=Pd, Pt) has been investigated in 1,2‐difluorobenzene solution using cyclic voltammetry and subsequently using the ferrocenium cation as a chemical redox agent. In the case of palladium, a mononuclear paramagnetic Pd(I) derivative was...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Troadec, Thibault, Tan, Sze‐yin, Wedge, Christopher J., Rourke, Jonathan P., Unwin, Patrick R., Chaplin, Adrian B.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4797707/
https://ncbi.nlm.nih.gov/pubmed/26879233
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201511467
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