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One‐Electron Oxidation of [M(P(t)Bu(3))(2)] (M=Pd, Pt): Isolation of Monomeric [Pd(P(t)Bu(3))(2)](+) and Redox‐Promoted C−H Bond Cyclometalation
Oxidation of zero‐valent phosphine complexes [M(P(t)Bu(3))(2)] (M=Pd, Pt) has been investigated in 1,2‐difluorobenzene solution using cyclic voltammetry and subsequently using the ferrocenium cation as a chemical redox agent. In the case of palladium, a mononuclear paramagnetic Pd(I) derivative was...
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| 出版年: | Angew Chem Int Ed Engl |
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| 主要な著者: | , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
John Wiley and Sons Inc.
2016
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4797707/ https://ncbi.nlm.nih.gov/pubmed/26879233 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201511467 |
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