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Enantioselective Organocatalytic Diels–Alder Trapping of Photochemically Generated Hydroxy‐o‐Quinodimethanes

The photoenolization/Diels–Alder strategy offers straightforward access to synthetically valuable benzannulated carbocyclic products. This historical light‐triggered process has never before succumbed to efforts to develop an enantioselective catalytic approach. Herein, we demonstrate how asymmetric...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Dell'Amico, Luca, Vega‐Peñaloza, Alberto, Cuadros, Sara, Melchiorre, Paolo
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4797706/
https://ncbi.nlm.nih.gov/pubmed/26797768
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201509472
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