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Light‐Driven Enantioselective Organocatalytic β‐Benzylation of Enals
A photochemical organocatalytic strategy for the direct enantioselective β‐benzylation of α,β‐unsaturated aldehydes is reported. The chemistry capitalizes upon the light‐triggered enolization of 2‐alkyl‐benzophenones to afford hydroxy‐o‐quinodinomethanes. These fleeting intermediates are stereoselec...
Sparad:
| I publikationen: | Angew Chem Int Ed Engl |
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| Huvudupphovsmän: | , , , |
| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
John Wiley and Sons Inc.
2017
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5412672/ https://ncbi.nlm.nih.gov/pubmed/28185401 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201612159 |
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