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Catalytic Insertion of Aldehydes into Dihalonitroacetophenones via Sequential Bond Scission-Aldol Reaction-Acyl Transfer
A catalytic process that provides dihalogenated nitro alcohols in up to 99% yield and with 100% atom economy is described. In-situ cleavage of dihalonitroacetophenones affords nitronates that undergo Lewis acid catalyzed addition to aldehydes. Final benzoylation renders the sequence irreversible and...
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| Publicado no: | Chem Commun (Camb) |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4760845/ https://ncbi.nlm.nih.gov/pubmed/26846436 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cc09753c |
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