Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions

To fully characterize the Co(III)–‘nitrene radical’ species that are proposed as intermediates in nitrene transfer reactions mediated by cobalt(II) porphyrins, different combinations of cobalt(II) complexes of porphyrins and nitrene transfer reagents were combined, and the generated species were stu...

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Pubblicato in:J Am Chem Soc
Autori principali: Goswami, Monalisa, Lyaskovskyy, Volodymyr, Domingos, Sérgio R., Buma, Wybren Jan, Woutersen, Sander, Troeppner, Oliver, Ivanović-Burmazović, Ivana, Lu, Hongjian, Cui, Xin, Zhang, X. Peter, Reijerse, Edward J., DeBeer, Serena, van Schooneveld, Matti M., Pfaff, Florian Felix, Ray, Kallol, de Bruin, Bas
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2015
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4750382/
https://ncbi.nlm.nih.gov/pubmed/25844713
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b01197
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