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Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions

To fully characterize the Co(III)–‘nitrene radical’ species that are proposed as intermediates in nitrene transfer reactions mediated by cobalt(II) porphyrins, different combinations of cobalt(II) complexes of porphyrins and nitrene transfer reagents were combined, and the generated species were stu...

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Détails bibliographiques
Publié dans:J Am Chem Soc
Auteurs principaux: Goswami, Monalisa, Lyaskovskyy, Volodymyr, Domingos, Sérgio R., Buma, Wybren Jan, Woutersen, Sander, Troeppner, Oliver, Ivanović-Burmazović, Ivana, Lu, Hongjian, Cui, Xin, Zhang, X. Peter, Reijerse, Edward J., DeBeer, Serena, van Schooneveld, Matti M., Pfaff, Florian Felix, Ray, Kallol, de Bruin, Bas
Format: Artigo
Langue:Inglês
Publié: 2015
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4750382/
https://ncbi.nlm.nih.gov/pubmed/25844713
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b01197
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