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Intramolecular Hydrogen Transfer Reactions Catalyzed by Pentamethylcyclopentadienyl Rhodium and Cobalt Olefin Complexes: Mechanistic Studies
The mechanism of intramolecular transfer dehydrogenation catalyzed by [Cp(*)M(VTMS)(2)] (1, M=Rh, 2, M=Co, Cp* = C(5)Me(5), VTMS = vinyltrimethylsilane) complexes has been studied using vinyl silane protected alcohols as substrates. Deuterium-labeled substrates have been synthesized and the regiosel...
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| Veröffentlicht in: | Polyhedron |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4742333/ https://ncbi.nlm.nih.gov/pubmed/26858471 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.poly.2015.07.076 |
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