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Solving the puzzling competition of the thermal C(2)–C(6) vs Myers–Saito cyclization of enyne-carbodiimides
The mechanism of the thermal cyclization of enyne-carbodiimides 7a–c has been studied computationally by applying the DFT method. The results indicate that enyne-carbodiimides preferentially follow the C(2)–C(6) (Schmittel) cyclization pathway in a concerted fashion although the Myers–Saito diradica...
Enregistré dans:
| Publié dans: | Beilstein J Org Chem |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Beilstein-Institut
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4734315/ https://ncbi.nlm.nih.gov/pubmed/26877807 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.6 |
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