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Synthesis of enantiopure 1,2-azido and 1,2-amino alcohols via regio- and stereoselective ring–opening of enantiopure epoxides by sodium azide in hot water
A practical and convenient method for the efficient and regio- and stereoselective ring-opening of enantiopure monosubstituted epoxides by sodium azide under hydrolytic conditions is reported. The ring–opening of enantiopure styryl and pyridyl (S)-epoxides by N(3)(−) in hot water takes place prefere...
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| Publicado no: | Tetrahedron Asymmetry |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4733893/ https://ncbi.nlm.nih.gov/pubmed/26843787 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetasy.2015.12.002 |
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