Loading...
Ruthenium-Catalyzed Asymmetric Hydrohydroxyalkylation of Butadiene: The Role of the Formyl Hydrogen Bond in Stereochemical Control
The catalyst generated in situ from RuH(2)(CO)(PPh(3))(3), (S)-SEGPHOS, and a chiral phosphoric acid promotes asymmetric hydrohydroxyalkylation of butadiene and affords enantioenriched α-methyl homoallylic alcohols. The observed diastereo- and enantioselectivities are determined by both the chiral p...
Na minha lista:
| Udgivet i: | J Am Chem Soc |
|---|---|
| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
|
| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4730892/ https://ncbi.nlm.nih.gov/pubmed/26107070 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b04844 |
| Tags: |
Tilføj Tag
Ingen Tags, Vær først til at tagge denne postø!
|