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Iron-Catalyzed Diastereoselective Intramolecular Olefin Aminobromination with Bromide Ion
A new iron-catalyzed diastereoselective aminobromination method is reported for both internal and terminal olefins (yield up to 90% and dr up to >20:1). In this transformation, a functionalized hydroxylamine and bromide ion were used as the nitrogen and bromine source, respectively. This method i...
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| Publicado no: | Synthesis (Stuttg) |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4720155/ https://ncbi.nlm.nih.gov/pubmed/26806984 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0034-1378719 |
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