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Iron(ii)-catalyzed asymmetric intramolecular olefin aminochlorination using chloride ion
An iron-catalyzed enantioselective and diastereoselective intramolecular olefin aminochlorination reaction is reported (ee up to 92%, dr up to 15 : 1). In this reaction, a functionalized hydroxylamine and chloride ion are utilized as nitrogen and chlorine sources, respectively. This new method toler...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4719767/ https://ncbi.nlm.nih.gov/pubmed/26807211 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00221d |
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