Crystal structure of bis­{μ(2)-[(2-imino­cyclo­pentyl­idene)methyl­idene]aza­nido-κ(2) N:N′}bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)zirconium(IV)] hexane monosolvate

The title compound, [Zr(2)(C(10)H(15))(4)(C(6)H(6)N(2))(2)]·C(6)H(14), was obtained by the stoichiometric reaction of adipo­nitrile with [Zr(C(10)H(15))(2)(η(2)-Me(3)SiC(2)SiMe(3))]. Intra­molecular nitrile–nitrile couplings and deprotonation of the substrate produced the (1-imino-2-enimino)­cyclo­p...

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Bibliographic Details
Published in:Acta Crystallogr E Crystallogr Commun
Main Authors: Becker, Lisanne, Spannenberg, Anke, Arndt, Perdita, Rosenthal, Uwe
Format: Artigo
Language:Inglês
Published: International Union of Crystallography 2015
Subjects:
Data Reports
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4719842/
https://ncbi.nlm.nih.gov/pubmed/26870433
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989015021234
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